Does it come with a short cage or "mid cage"? A mid cage will take a 32t (maybe 34t?), short cage is spec'd to 28t, but I've used a 30t and it worked fine. I tried 32t on that same short cage and it worked, but not very well. Hope that helps some. Henry
If you have a medium cage derailleur it will work with an adjustment of the "b" screw on the derailleur. You might make a short cage work with a 11-32 but it will be close. I tried with a 11-36 but no go. Remember to make sure you have enough chain to cover the large front/large rear gear combination.
Ask the bike shop or whoever you are buying the bike from. A mid cage model has the "GS" designation. Short cage is "SS". *edit to add - my Grade 105 came stock with mid cage, 11-32t with no B screw adjustment required.
If you get cog/pulley interference but the RD can wrap enough chain then take a look at the Wolftooth RoadLink. You should be able to run a 36 easily with that. My friend w/a Diverge is running an 11-36 w/o the RoadLink and an Ultegra GS RD. A B-screw adjustment was all that was necessary. He is running a 46/34 crankset.
I made this same change on my Tamland 1. I felt like it would be very close to working but I went ahead and bought the new 5701 GS and put it on with a new SRAM cassette.